CV A. Voituriez

  • 2016 – present : CNRS research director DR2 at ICSN
  • 2011 – 2016 : CNRS research associate CR1 at ICSN
  • 2012 : HDR diploma (habilitation to conduct research). Jury : Henri Kagan, Didier Bourissou, Olivier Baudoin, Laurent Micouin, Max Malacria, Cyrille Kouklovsky and Angela Marinetti.
  • 2007 – 2011 : CNRS research associate CR2 at ICSN
  • 2006 – 2007 : Post-doctoral Fellow at UPMC, Paris, France (F. Chemla)
  • 2004 – 2006 : Post-doctoral Fellow at University of Montréal, Québec (A. B. Charette)
  • 2001 – 2004 : Ph.D. degree at University of Paris-Sud, Orsay, France (E. Schulz)

1) Synthesis of new chiral phosphines with helical and planar chirality.

2) Enantioselective phosphine organocatalysis.

3) Synthesis and applications of phospha-helicenes.

4) Asymmetric gold-catalyzed reactions.

5) Organometallic chemistry.

6) Medicinal chemistry and total synthesis.

  • Supervision and co-supervision of 4 Master students, 10 PhD students and 6 postDocs.
  • Teaching experience at Paris-Saclay University: ~ 40h/year.
  • Council member of the Labex Charm3at (2012-…) and ICSN lectures (2012-2015; 2019-…).
  • Organization: Summer School Charm3at 2015, 2017 and 2019; 5th French-Czech “Vltava” Symposium 2014; 14th ICSN Symposium 2015.
  • Board member of the « French-Japanese Society of Medicinal and Fine Chemistry » (2019-…).
  • National funding: Coordinator of the ANR project HUISPHOS (2014-2017) “New developments in phosphine organocatalysis” and the ANR SWITCH-PHOS (2017-2021) “Bimetallic complexes of photoswitchable phosphines and uses in catalysis”.
  • Industrial funding (2011-2012, Sanofi-Aventis).
  • “Academic Editor” of the “Heteroatom Chemistry” Journal.
    • Total of 76 papers with lecture committee, 3150 citations, h-index = 30 (WoS 07/2020).
    • 49 oral communications and conferences (8 Invitations in national and international congresses, 24 Invited lectures in Universities, 17 oral communications in symposium and congress).
    • 2016 : Distinguished Member of the French Chemical Society
    • 2019 : ACS Green Chemistry Institute Pharmaceutical Roundtable Award
    • 2020 : Recipient of the program « Discovery China » from the French Embassy in China
    • 2020 : “Jean–Marie Lehn Award” from the Organic Chemistry division of the French Chemical Society (http://www.societechimiquedefrance.fr/Laureats-896.html)

     

  • Lorton, C.; Castanheiro, T.; Voituriez, A.* J. Am. Chem. Soc. 2019, 141, 10142. « Catalytic and Asymmetric Process via PIII/PV=O Redox Cycling: Access to (Trifluoromethyl)cyclobutenes via a Michael Addition/Wittig Olefination Reaction »

  • Han, X. ; Saleh, N. ; Retailleau, P. ; Voituriez, A.* Org. Lett. 2018, 20, 4584. « Phosphine-Catalyzed Reaction Between 2-Aminobenzaldehydes and Dialkyl Acetylenedicarboxylates : Synthesis of 1,2-Dihydroquinoline Derivatives and Toward the Development of an Olefination Reaction ».
  • Lorton, C. ; Voituriez, A.* J. Org. Chem. 2018, 83, 5801. « Phosphine-Promoted Synthesis of 9H-Pyrrolo[1,2-a]indole Derivatives via an γ-Umpolung Addition/Intramolecular Wittig Reaction ».
  • Arif, T. ; Cazorla, C. ; Bogliotti, N. ; Saleh, N. ; Blanchard, F. ; Gandon, V. ; Métivier, R. ; Xie, J. ; Voituriez, A. ;* Marinetti A.* Cat. Sci. Catal. 2018, 8, 710. « Bimetallic gold(I) complexes of photoswitchable phosphines : synthesis and uses in cooperative catalysis ».
  • Magné, V. ; Lorton, C. ; Marinetti, A. ; Guinchard, X. ; Voituriez, A.* Org. Lett. 2017, 19, 4794. « Short Enantioselective Total Synthesis of (−)-Rhazinilam Using a Gold(I)-Catalyzed Cyclization ».
  • Saleh, N. ; Blanchard, F. ; Voituriez, A.* Adv. Synth. Catal. 2017, 359, 2304. « Synthesis of Nitrogen-Containing Heterocycles and Cyclopentenone Derivatives via Phosphine-Catalyzed Michael Addition/Intramolecular Wittig Reaction ».
  • Wu, Z. ; Lebœuf, D. ; Retailleau, P. ; Gandon, V. ;* Marinetti, A. ; Voituriez, A.* Chem. Commun. 2017, 53, 7026. « Enantioselective gold(I)-catalyzed rearrangement of cyclopropyl-substituted 1,6-enynes into 2-oxocyclobutyl-cyclopentanes ».
  • Saleh, N. ; Voituriez, A.* J. Org. Chem. 2016, 81, 4371. « Synthesis of 9H-Pyrrolo[1,2-a]indole and 3H-Pyrrolizine Derivatives via a Phosphine-Catalyzed Umpolung Addition/Intramolecular Wittig Reaction ».
  • Wu, Z. ; Isaac, K. ; Retailleau, P. ; Betzer, J.-F. ;* Voituriez, A. ;* Marinetti, A. Chem. Eur. J. 2016, 22, 3278. « Planar Chiral Phosphoramidites with Paracyclophane Scaffold : Synthesis, Gold(I) Complexes and Enantioselective Cycloisomerization of Dienynes ».
  • Tlili, A. ; Voituriez, A. ;* Marinetti, A. ;* Thuéry, P. ; Cantat, T.* Chem. Commun. 2016, 52, 7553. « Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2 ».
  • Aillard P. ; Dova, D. ; Magné, V. ; Retailleau, P. ; Cauteruccio, S. ; Licandro, E. ; Voituriez, A. ;* Marinetti, A.* Chem. Commun. 2016, 52, 10984. « The synthesis of substituted phosphathiahelicenes via regioselective bromination of a preformed helical scaffold : a new approach to modular ligands for enantioselective gold-catalysis ».
  • Magné, V. ; Blanchard, F. ; Marinetti, A. ; Voituriez, A. ;* Guinchard, X.* Adv. Synth. Catal. 2016, 358, 3355. « Synthesis of Spiro[piperidine-3,3’-oxindoles] via Gold(I)-Catalyzed Dearomatization of N-Propargyl- and N-Homoallenyl-2-bromotryptamines ».
  • Fourmy, K. ; Voituriez, A.* Org. Lett. 2015, 17, 1537. « Catalytic Cyclization Reactions of Huisgen Zwitterion with α‑Ketoesters by in Situ Chemoselective Phosphine Oxide Reduction ».
  • Gicquel, M. ; Zhang, Y. ; Aillard, P. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, M.* Angew. Chem. Int. Ed. 2015, 54, 5470. « Phosphahelicenes in Asymmetric Organocatalysis : [3+2] Cyclizations of -Substituted Allenes and Electron-Poor Olefins ».
  • Aillard P. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Chem. Eur. J. 2015, 21, 11989. « Synthesis of New Phosphahelicene Scaffolds and Development of Gold(I)-Catalyzed Enantioselective Allen-ene Cyclizations ».
  • Nuter, F. ; Dimé, A.K.D. ; Chen, C. ; Bounaadja, L. ; Mouray, E. ; Florent, I. ; Six, Y. ;* Buriez, O. ;* Marinetti, A. ;* Voituriez, A.* Chem. Eur. J. 2015, 21, 5584. « An Access to New Endoperoxide Derivatives by Electrochemical Oxidation of Substituted 3-Azabicyclo[4.1.0]hept-4-enes ».
  • Yavari, K. ; Aillard, P. ; Zhang, Y. ; Nuter, F. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Angew. Chem. Int. Ed.2014, 53, 861. « Helicenes with Embedded Phosphole Units in Enantioselective Gold Catalysis ».
  1. Enantioselective gold(I)-catalyzed cyclization/intermolecular nucleophilic additions of 1,5-enyne derivatives. Han, X.; Retailleau, P.; Gandon, V.;* Voituriez, A.* submitted

 

  1. Chiral Phosphathiahelicenes: Improved Synthetic Approach and Uses in Enantioselective Gold(I)-Catalyzed [2+2] Cycloadditions of N-Homoallenyl Tryptamines. Magné, V.; Sanogo, Y.; Demmer, C. S.; Retailleau, P.; Marinetti, A.; Guinchard, X.;* Voituriez, A.* ACS Catal., 2020, 1021/acscatal.0c01819.

 

  1. Tethered Counterion-Directed Catalysis: Merging the Chiral Ion-Pairing and Bifunctional Ligand Strategies in Enantioselective Gold(I) Catalysis. Zhang, Z.; Smal, V.; Retailleau, P.; Voituriez, A.; Frison, G.; Marinetti, A. Guinchard, X. Am. Chem. Soc. 2020, 142, 3797.

DOI 10.1021/jacs.9b11154

 

74. Enantioselective Gold(I)-Catalyzed Hydrative Cyclizations of N-Propargyl Ynamides into 3,6-Dihydropyridinones. Febvay, J.; Sanogo, Y.; Retailleau, P.; Gogoi, M.P.; Sahoo, K.; Marinetti, A.;* Voituriez, A.* Org. Lett. 2019, 21, 9281.

10.1021/acs.orglett.9b02644

 

  1. Phosphahelicenes with (thio)phosphinic acid and ester functions via the oxidative photocyclisation approach. Febvay, J.; Demmer, C.; Retailleau, P.; Crassous, J.; Abella, L.; Autschbach, J.;* Voituriez, A.;* Marinetti A.* Chem. Eur. J. 2019, 25, 15609.
    10.1002/chem.201903750

 

  1. Thioarylative Radical Cyclization of Yne-Dienone. Mallick, R.K.; Dutta, S.; Vanjari, R.; Voituriez, A.; Sahoo, A.K. J. Org. Chem. 2019, 84, 10509.

https://dx.doi.org/10.1021/acs.joc.9b01445

 

  1. Synthesis and Applications of 9H-Pyrrolo[1,2-a]indole and 9H-Pyrrolo[1,2-a]indol-9-one Derivatives. Lorton C.; Voituriez, A.* Eur. J. Org. Chem. 2019, 5133.

https://dx.doi.org/10.1002/ejoc.201900626

 

  1. Synthesis and X-ray diffraction study of a chiral bis-phosphahelicene palladium (II) complex. Sanogo, Y.; Aillard, P.; Retailleau, P.; Voituriez, A.;* Marinetti, A.* Chirality 2019, 8, 561.

https://dx.doi.org/10.1002/chir.23100

 

  1. Catalytic and Asymmetric Process via PIII/PV=O Redox Cycling: Access to (Trifluoromethyl)cyclobutenes via a Michael Addition/Wittig Olefination Reaction. Lorton, C.; Castanheiro, T.; Voituriez, A.* J. Am. Chem. Soc. 2019, 141, 10142.

https://dx.doi.org/10.1021/jacs.9b02539

 

  1. Phosphahelicenes: from chiroptical and photophysical properties to OLED applications. Yavari, K.; Delaunay, W.; De Rycke, N.; Reynaldo, T.; Aillard, P.; Srebro-Hooper, M.;* Chang, V. Y.; Muller, G.; Tondelier, D.; Geffroy, B.; Voituriez, A.;* Marinetti, A.;* Hissler, M.;* Crassous J.* Eur. J. 2019, 20, 5303.

https://dx.doi.org/10.1002/chem.201806140

 

  1. Tuning the Structure of Phosphahelicenes for Targeted Applications in Enantioselective Phosphine Organocatalysis. Aillard, P.; Gicquel, M.; Yavari, K.; Retailleau, P.; Voituriez, A.;* Marinetti, A.* Eur. J. Org. Chem. 2018, 5853.

https://dx.doi.org/10.1002/ejoc.201800438

 

66. Inhibition of p53-Murine Double Minute 2 (MDM2) Interactions with 3,3′-Spirocyclopentene Oxindole Derivatives. Gicquel, M. ; Gomez, C. ; Garcia Alvarez, M. C. ; Pamlard, O. ; Guérineau, V. ; Jacquet, E. ; Bignon, J. ;* Voituriez, A. ;* Marinetti, A.* J. Med. Chem. 201861, 9386.

DOI : 10.1021/acs.jmedchem.8b01137

65. Phosphine-Catalyzed Reaction between 2‑Aminobenzaldehydes and Dialkyl Acetylenedicarboxylates : Synthesis of 1,2-Dihydroquinoline Derivatives and Toward the Development of an Olefination Reaction. Han, X. ; Saleh, N. ; Retailleau, P. ; Voituriez, A.* Org. Lett. 201820, 4584.

DOI : 10.1021/acs.orglett.8b01870

64. Phosphine-Promoted Synthesis of 9H-Pyrrolo[1,2-a]indole Derivatives via an γ-Umpolung Addition/Intramolecular Wittig Reaction. Lorton, C. ; Voituriez, A.* J. Org. Chem. 201883, 5801.

DOI : 10.1021/acs.joc.8b00457

63. Gold-Catalyzed Synthesis of 2-Sulfenylspiroindolenines. Magné, V. ; Retailleau, P. ; Marinetti, A. ; Voituriez, A. ; Guinchard, X. * Molbank 2018M985, doi:10.3390/M985.

DOI : 10.3390/M985

62. Revised theoretical model on enantiocontrol in phosphoric acid catalyzed H-transfer hydrogenation of quinolone.Pastor, J. ; Rezabal, E. ; Voituriez, A. ; Betzer, J.-F. ;* Marinetti, A. ; Frison, G.* J. Org. Chem. 201883, 2779.

DOI : 10.1021/acs.joc.7b03248

61. Bimetallic gold(I) complexes of photoswitchable phosphines : synthesis and uses in cooperative catalysis. Arif, T. ; Cazorla, C. ; Bogliotti, N. ; Saleh, N. ; Blanchard, F. ; Gandon, V. ; Métivier, R. ; Xie, J. ; Voituriez, A. ;* Marinetti A.* Cat. Sci. Catal. 20188, 710.

DOI : 10.1039/c7cy01614j

60. Diastereoselective Synthesis of Planar Chiral Phosphoramidites with a Ferrocenophane Scaffold. Neel, M. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Organometallics 201837, 797.

DOI : 10.1021/acs.organomet.7b00700

59. Synthesis of Spiroindolenines via Regioselective Gold(I)-Catalyzed Cyclizations of N-Propargyl Tryptamines.Magné, V. ; Marinetti, A. ; Gandon, V. ; Voituriez, A. ; Guinchard, X. Adv. Synth. Catal. 2017359, 4036.

DOI : 10.1002/adsc.201700932

58. Photochemical [2+2] Cyclization of Helical Phosphinamides in Solution and in the Solid State. Demmer, C. S. ; Aillard, P. ; Febvay, J. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* ChemPhotoChem 20171, 535.

DOI : 10.1002/cptc.201700148

57. Short Enantioselective Total Synthesis of (−)-Rhazinilam Using a Gold(I)-Catalyzed Cyclization. Magné, V. ; Lorton, C. ; Marinetti, A. ; Guinchard, X. ; Voituriez, A.* Org. Lett. 201719, 4794.

DOI : 10.1021/acs.orglett.7b02210

56. Enantioselective gold(I)-catalyzed rearrangement of cyclopropyl-substituted 1,6-enynes into 2-oxocyclobutyl-cyclopentanes. Wu, Z. ; Lebœuf, D. ; Retailleau, P. ; Gandon, V. ;* Marinetti, A. ; Voituriez, A.* Chem. Commun. 201753, 7026.

DOI : 10.1039/c7cc03234j

55. Synthesis of Nitrogen-Containing Heterocycles and Cyclopentenone Derivatives via Phosphine-Catalyzed Michael Addition/Intramolecular Wittig Reaction. Saleh, N. ; Blanchard, F. ; Voituriez, A.* Adv. Synth. Catal. 2017359, 2304.

DOI : 10.1002/adsc.201700313

54. Catalytic Uses of Helicenes Displaying Phosphorus Functions. Demmer, C.S. ; Voituriez, A. ; Marinetti, A. C. R. Chim. 201720, 860.

DOI : 10.1016/j.crci.2017.04.002

53. Silyl-Substituted Planar Chiral Phosphoric Acids with Ferrocene-bridged Paracyclophane Frameworks : Synthesis, Characterization, and Uses in Enantioselective aza-Friedel-Crafts Reactions. Stemper, J. ; Isaac, K. ; Ghosh, N. ; Lauwick, L. Le Duc, G. ; Retailleau, P. ; Voituriez, A. ; Betzer J. F. ; Marinetti A. Adv. Synth. Catal. 2017359, 519.

DOI : 10.1002/adsc.201600920

52. Synthesis of Spiro[piperidine-3,3’-oxindoles] via Gold(I)-Catalyzed Dearomatization of N-Propargyl- and N-Homoallenyl-2-bromotryptamines. Magné, V. ; Blanchard, F. ; Marinetti, A. ; Voituriez, A. ;* Guinchard, X.* Adv. Synth. Catal. 2016358, 3355.

DOI : 10.1002/adsc.201600398

51. From Phosphine-Promoted to Phosphine-Catalyzed Reactions by in situ Phosphine Oxide Reduction. Voituriez, A. ;* Saleh, N. Tetrahedron Lett. 201657, 4443.

DOI : 10.1016/j.tetlet.2016.08.036

50. The synthesis of substituted phosphathiahelicenes via regioselective bromination of a preformed helical scaffold : a new approach to modular ligands for enantioselective gold-catalysis. Aillard P. ; Dova, D. ; Magné, V. ; Retailleau, P. ; Cauteruccio, S. ; Licandro, E. ; Voituriez, A. ;* Marinetti, A.* Chem. Commun. 201652, 10984.

DOI : 10.1039/c6cc04765c

49. Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2. Tlili, A. ; Voituriez, A. ;* Marinetti, A. ;* Thuéry, P. ; Cantat, T.* Chem. Commun. 201652, 7553.

DOI : 10.1039/c6cc02809h

48. Synthesis of 9H-Pyrrolo[1,2-a]indole and 3H-Pyrrolizine Derivatives via a Phosphine-Catalyzed Umpolung Addition/Intramolecular Wittig Reaction. Saleh, N. ; Voituriez, A.* J. Org. Chem. 201681, 4371.

DOI : 10.1021/acs.joc.6b00473

47. Tetrathia[7]helicene phosphorus derivatives : experimental and theoretical investigations of electronic properties, and preliminary application as organocatalysts. Dova, D. ; Viglianti, L. ; Mussini, P. R. ; Prager, S. ; Dreuw, A. ; Voituriez, A. ; Licandro E. ; Cauteruccio S. Asian J. Org. Chem. 20165, 537.

DOI : 10.1002/ajoc.201600025

46. Planar Chiral Phosphoramidites with Paracyclophane Scaffold : Synthesis, Gold(I) Complexes and Enantioselective Cycloisomerization of Dienynes. Wu, Z. ; Isaac, K. ; Retailleau, P. ; Betzer, J. F. ;* Voituriez, A. ;* Marinetti, A. Chem. Eur. J. 201622, 3278.

DOI : 10.1002/chem.201504658

45. Use of Planar Chiral Ferrocenylphosphine-Gold(I) Complexes in the Asymmetric Cycloisomerization of 3-Hydroxylated 1,5-Enynes. Wu, Z. ; Retailleau, P. ; Gandon, V. ; Voituriez, A. ;* Marinetti, A.* Eur. J. Org. Chem. 2016, 70.

DOI : 10.1002/ejoc.201501121

44. Synthesis of New Phosphahelicene Scaffolds and Development of Gold(I)-Catalyzed Enantioselective Allen-ene Cyclizations. Aillard P. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Chem. Eur. J. 201521, 11989.

DOI : 10.1002/chem.201501697

43. Phosphahelicenes in Asymmetric Organocatalysis : [3+2] Cyclizations of γ-Substituted Allenes and Electron-Poor Olefins. Gicquel, M. ; Zhang, Y. ; Aillard, P. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Angew. Chem. Int. Ed. 201554, 5470.

DOI : 10.1002/anie.201500299

42. Catalytic Cyclization Reactions of Huisgen Zwitterion with α‑Ketoesters by in Situ Chemoselective Phosphine Oxide Reduction. Fourmy, K. ; Voituriez, A.* Org. Lett. 201517, 1537.

DOI : 10.1021/acs.orglett.5b00426

41. An Access to New Endoperoxide Derivatives by Electrochemical Oxidation of Substituted 3-Azabicyclo[4.1.0]hept-4-enes. Nuter, F. ; Dimé, A.K.D. ; Chen, C. ; Bounaadja, L. ; Mouray, E. ; Florent, I. ; Six, Y. ;* Buriez, O. ;* Marinetti, A. ;* Voituriez, A.* Chem. Eur. J. 201521, 5584.

DOI : 10.1002/chem.201406138

40. Phosphine Organocatalysis for the Synthesis of Spirocyclic Compounds. Voituriez, A. ;* Marinetti, A. ;* Gicquel, M. Synlett 201526, 1424.

DOI : 10.1055/s-0034-1379251

39. Helicene-like chiral auxiliaries in asymmetric catalysis. Aillard P. ; Voituriez, A. ; Marinetti, A. Dalton Trans. 201443, 15263.

DOI : 10.1039/c4dt01935k

38. Phospha-Thiahelicenes : Synthesis and Uses in Enantioselective Gold Catalysis. Aillard P. ; Voituriez, A. ;* Dova, D. ; Cauteruccio, S. ; Licandro, E. ; Marinetti, A.* Chem. Eur. J. 201420, 12373.

DOI : 10.1002/chem.201402822

37. A [2+2+2] cyclization strategy for the synthesis of phosphorus embedding [6]helicene-like structures. Aillard P. ; Retailleau P. ; Voituriez A. ;* Marinetti, A.* Chem. Commun. 201450, 2199.

DOI : 10.1039/c3cc48943d

36. Helicenes with Embedded Phosphole Units in Enantioselective Gold Catalysis. Yavari, K. ; Aillard, P. ; Zhang, Y. ; Nuter, F. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Angew. Chem. Int. Ed. 201453, 861.

DOI : 10.1002/anie.201308377

35. Thiophostone-Derived Brønsted Acids in the Organocatalyzed Transfer Hydrogenation of Quinolines : Influence of the P-Stereogenicity. Ferry, A. ; Stemper, J. ; Marinetti, A. ; Voituriez, A. ;* Guinchard, X.* Eur. J. Org. Chem. 2014, 188.

DOI : 10.1002/ejoc.201301253

34. Development of Chiral Phosphoric Acids based on Ferrocene-Bridged Paracyclophane Frameworks. Stemper, J. ; Isaac, K. ; Pastor, J. ; Frison, G. ; Retailleau, P. ; Voituriez, A. ; Betzer, J.-F. ; Marinetti, A. Adv. Synth. Catal. 2013355, 3613.

DOI : 10.1002/adsc.201300697

33. Heterohelicenes with embedded P-chiral 1H-phosphindole or dibenzophosphole units : diastereoselective photochemical synthesis and structural characterization. Yavari, K. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Chem. Eur. J. 201319, 9939.

DOI : 10.1002/chem.201300844

32. Synthesis of 3,3′-Spirocyclic Oxindoles via Phosphine Catalyzed [4 + 2] Cyclizations. Gicquel, M. ; Gomez, C. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Org. Lett. 201315, 4002.

DOI : 10.1021/ol401798w

31. [3,3]Paracyclophanes as Planar Chiral Scaffolds for the Synthesis of New Phosphoric Acids. Stemper, J. ; Isaac, K. ; Duret, V. ; Retailleau, P. ; Voituriez, A. ; Betzer J.-F. ; Marinetti A. Chem. Commun. 201349, 6084.

DOI : 10.1039/c3cc41496e

30. Platinum(II) catalyzed enantioselective cycloisomerizations of 3-hydroxylated 1,5-enynes. Zhang, Y. ; Jullien, H. ; Brissy, D. ; Retailleau, P. ; Voituriez, A., Marinetti, A. Chem. Cat. Chem. 20135, 2051.

DOI : 10.1002/cctc.201200743

29. Phosphine organocatalysis in the synthesis of natural products and bioactive compounds. Gomez, C. ; Betzer, J.-F. ; Voituriez, A. ; Marinetti, A. Chem. Cat. Chem. 20135, 1055.

DOI : 10.1002/cctc.201200442

28. Phosphine-Catalyzed Synthesis of 3,3-Spirocyclopenteneoxindoles from γ-Substituted Allenoates : Systematic Studies and Targeted Applications. Gomez, C. ; Gicquel, M. ; Carry, J.-C. ; Schio, L. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* J. Org. Chem. 201378, 1488.

DOI : 10.1021/jo302460d

27. 1H-Phosphindoles as structural units in the synthesis of chiral helicenes. Yavari, K. ; Moussa, S. ; Ben Hassine, B. ; Retailleau, P. ; Voituriez, A. ; Marinetti, A. Angew. Chem. Int. Ed. 201251, 6748.

DOI : 10.1002/anie.201202024

26. Enantioselective, transition metal catalyzed cycloisomerizations. Marinetti, A. ; Jullien, H. ; Voituriez, A. Chem. Soc. Rev. 201241, 4884.

DOI : 10.1039/c2cs35020c

25. Stereoselective synthesis of planar chiral 2,2’-diarylsubstituted ferrocene derivatives as precursors for new 2-phospha[3]ferrocenophanes. Neel, M. ; Panossian, A. ; Voituriez, A. ; Marinetti, A. J. Organomet. Chem. 2012716, 187.

DOI : /10.1016/j.jorganchem.2012.06.033

24. Heterocyclic Spiranes and Dispiranes via Enantioselective Phosphine Catalyzed [3+2] Annulations. Duvvuru, D. ; Pinto, N. ; Gomez, C. ; Betzer, J. –F. ; Retailleau, P. ; Voituriez, A. ;* Marinetti, A.* Adv. Synth. Catal. 2012354, 408.

DOI : 10.1002/adsc.201100748

23. Phosphine-Catalyzed [3+2] Cyclizations : Applications to the Enantioselective Synthesis of Cyclopentene-Fused Chromanones and Dihydroquinolinones. Neel, M. ; Gouin, J. ; Voituriez, A. ; Marinetti, A. Synthesis 201112, 2003.

DOI : 10.1055/s-0030-1260466

22. Organocatalytic Enantioselective Desymmetrization of Cyclic Enones via Phosphine Promoted [3+2] Annulations.Pinto, N. ; Retailleau, P. ; Voituriez, A. ; Marinetti A. Chem. Commun. 201145, 1015.

DOI : 10.1039/c0cc03164j

21. An Organocatalytic [3+2] Cyclisation Strategy for the Highly Enantioselective Synthesis of Spirooxindoles. Voituriez, A. ; Pinto, N. ; Neel, M. ; Retailleau, P. ; Marinetti A. Chem. Eur. J. 201016, 12541.

DOI : 10.1002/chem.201001791

20. Studies on the asymmetric, phosphine-promoted [3+2] annulations of allenic esters with 2-aryl-1,1-dicyanoalkenes.Schuler, M. ; Voituriez, A. ; Marinetti, A. Tetrahedron : Asymmetry 201021, 1569.

doi.org/10.1016/j.tetasy.2010.04.014

19. Expanding the Scope of Enantioselective FerroPHANE-promoted [3+2] Annulations on α,β-unsaturated Ketones.Pinto, N. ; Neel, M. ; Panossian, A. ; Retailleau, P. ; Frison, G. ; Voituriez, A. ; Marinetti A. Chem. Eur. J. 201016, 1033.

DOI : 10.1002/chem.200901893

18. Enantioselective Phosphine Organocatalysis. Marinetti, A. ; Voituriez, A. Synlett 20102, 174.

DOI : 10.1055/s-0029-1219157

17. Synthesis of Chiral 2-Phospha[3]ferrocenophanes and their Behaviour as Organocatalysts in [3+2] Cyclization Reactions. Voituriez, A. ; Panossian, A. ; Fleury-Brégeot, N. ; Retailleau, P. ; Marinetti, A. Adv. Synth. Catal. 2009351, 1968.

DOI : 10.1002/adsc.200900193

16. A facile synthesis of 4-methylene-1,3-oxazolidines from γ-hydroxybutynoate and N-tosylimines. Fleury-Brégeot, N. ; Voituriez, A. ; Retailleau, P. ; Marinetti, A. Tetrahedron Letters 200950, 4700.

doi:10.1016/j.tetlet.2009.06.009

15. 2-Phospha[3]ferrocenophanes with Planar Chirality : Synthesis and Use in Enantioselective Organocatalytic [3 + 2] Cyclizations. Voituriez, A. ; Panossian, A. ; Fleury-Brégeot, N. ; Retailleau, P. ; Marinetti, A. J. Am. Chem. Soc. 2008130, 14030.

DOI : 10.1021/ja806060a

CNRS Research Associate DR2

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